Smoke and Mirrors: Ultra-Rapid-Scan FT-IR
Spectrometry
There are two types of systems for which time-resolved measurements are
desired. The two types are distinguished by repeatability. Some systems are intrinsically
very repeatable - these would probably include stretching of polymers within their elastic
limit, and optical perturbation of systems which undergo a photocycle. Some systems such
as explosions or process streams are intrinsically non-repeatable. There can also be some
overlap between repeatable and non-repeatable events. If a laser used to trigger
photocycles in a sample has a large shot-to-shot variation, then the repeatability will be
poor. Combustion systems, even those where the reactants can be replaced from
shot-to-shot, tend to have large variations. Photocycles of certain protein systems may
have excellent reproducibility from shot-to-shot but photodegrade rapidly. The various
step-scan and stroboscopic techniques can produce excellent results in cases where
repeatability is good. They do not produce data in real time and very poor results are
obtained when the system under study is unstable.
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